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CSE · Paper I · Thermal & Statisticalcse-2014-subject-04-003

Degrees of freedom — UPSC Physics Optional CSE 2014 Paper I

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Consider a system of free gas particles having f degrees of freedom. Use equipartition theorem to establish the relation f=\frac{2}{\left(\dfrac{C_p}{C_V}-1\right)}, where C_p and C_V are molar specific heats at constant pressure and constant volume respectively. Obtain the values of \dfrac{C_p}{C_V} for diatomic and triatomic gases.

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